Ruthenium catalysts

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.

cis-cis- 1,3,5-triaminocyclohexane (30.0 nig, 0.232 mmol) was added to an ampoule charged with dichlorotris(triphenylphosphane)ruthenium(II) (196 mg, 0.204 mmol) dissolved in dichloromethane (20 mL), causing an instant colour change from black to orange. The solution was stirred at 50C for 4 days in the sealed vessel, during whichtime the solution changed colour to yellow and a white precipitate formed. The precipitate was removed by filtration and the filtrate reduced in volume to approx. 1 mL in vacuo. The product was precipitated by addition of pentane (20 mL) as an orange powder, and washed twice with pentane (20 mL). Yield: 115 mg (86.8 %, 0.177 mmol of RuCl2(K3-c -tach)(PPh3).CH2Cl2). NMR Spectroscopy Cs minor plane H NMR (CD2C12, 399.8 MHz, 293K) delta 7.85 (app t, HH = 7.5 Hz, VHP = 5.8 Hz, VHH = 1.5 Hz, 6H, P/Vz3, Ar2), 7.36 (m, 9H, Rho/>Lambda3, Ar3 + Ar4), 4.77 (s, 2H, NH2, N1), 3.90 (bs, 1Eta, CH, Cy1), 2.92 (s, 2Eta, CH, Cy2), 2.65 (d, VHH = 10.6 Hz, 2H, N N2), 1.92 (s, 4H, CH2, Cy3), 1.85 (d, HH = 10.6 Hz, 2H, NH2, N2), 1.62 (d, VHH = 15.3 Hz, 1H, CH2, Cy4), 1.00 (d, VHH = 15.3 Hz, 1H, CH2, Cy4); 31Rho{} NMR (CD2C12, 161.8 MHz, 293 ) delta 66.0 (s, IP, PPh3); “Ci’H} NMR (CD2C12, 100.5 MHz, 293K) delta 136.2 (d, ‘Jpc = 36.0 Hz, VPh3, Ar1), 134.2 (d, VPC = 10.1 Hz, VPh3, Ar2), 129.5 (d, VPC = 1.85 Hz, ?P 3, Ar4), 128.8 (d, VPC = 8.7 Hz, ?Ph3, Ar3), 44.0 (s, CH, Cy1), 43.8 (s, CH, Cy2), 35.0 (s, CH2, Cy3), 33.6 (s, CH2, Cy4).Mass Spectrometry ESI-MS: m/z 569.1186 ([RuCl(NCMe)( 3-c i-tach)(PPh3)l+. Calc 569.1173, 100 %), 528.0919 ([RuCl(K3-c-tach)(PPh3)]+; 528.0907, 25), 246.5607 ([RU(K3-CW- tach)(PPh3)]2+, 246.5608, 10). Infra-Red Spectroscopy ATR-IR: (cm 1) 3462, 3283, 3240, 3050, 2888, 1649, 1588, 1480, 1432 (P-Ph), 1367, 1346, 1270, 1211, 1183, 1156, 1089, 1027, 968, 905. Elemental Analysis CH2C12 c / % H / % N / % Found 46.25 4.92 6.43 0 51.15 5.37 7.46 1 46.31 4.97 6.48 Table 0.1: CHN Elemental analysis for RuCl2(K3-cw-tach)(PPh3)

As the paragraph descriping shows that 15529-49-4 is playing an increasingly important role.

Reference£º
Patent; UNIVERSITY OF YORK; GAMBLE, Aimee, Joanna; LYNAM, Jason, Martin; WALTON, Paul, Howard; WO2013/38134; (2013); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

15529-49-4, Dichlorotris(triphenylphosphino)ruthenium (II) is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

A 50 ml three-necked flask equipped with a stirring reflux device was charged with 1 mmol of 2-dicyclohexylphosphine aniline,1.2 mmol of p-chlorobenzyl alcohol, 1 mmol of 1,1′-diphenylphosphinoferrocene, 1 mmol of RuCl2 (PPh3) 3, 1.2 mmol of triethylamine and 20 ml of toluene at a temperature of 110 C. and heated under a nitrogen atmosphere for 24 hAfter cooling and filtration, the resulting solid was recrystallized from a mixed solvent of CH 2 Cl 2 and petroleum ether to give product 20 in a yield of 86%.

The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Patent; Luoyang Normal College; Li Hongmei; Xu Chen; Zu Enpu; Xiao Zhiqiang; Han Xin; (12 pag.)CN104804048; (2017); B;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.

RuCl2(PPh3)3(480 mg, 0.5 mmol) was placed in a 25 mL flask filled with argon. THF(12.5 mL) and (R,R)-DPEN (127 mg, 0.6 mmol) were then added. The mixturewas degassed and stirred under argon at 25 oC for 6 h. After removalof turbidity by filtration, n-hexane (30 mL) was added, and a light yellowsolid was obtained. The supernatant was removed and the resulting solid wasdried under reduced pressure to give analytically pure 1f (442 mg, 97% yield). 2.1. RuCl2(R,R)-DPEN(PPh3)2 1f1H NMR (300MHz, C6D6, ppm), delta: 7.95-7.92 (m,12H), 6.97-6.95 (m, 18H), 6.74 (br, 10H), 4.61-4.4.59(m, 2H), 4.12-4.09 (m, 2H), 3.59-3.56 (m, 2H); 31P NMR (121MHz, C6D6, ppm), delta: 45.7.

The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Li, Xuefeng; Ma, Yaping; Xing, Zhikui; Tang, Ning; Zhu, Jin; Deng, Jingen; Tetrahedron Letters; vol. 55; 29; (2014); p. 3868 – 3872;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.15529-49-4,Dichlorotris(triphenylphosphino)ruthenium (II),as a common compound, the synthetic route is as follows.

Example B2: Preparation of [(CI)2Ru(Pphenyl3)(ligand L2)], K2tolueneyl 272.5 mg (0.284 mmol) of dichlorotris(triphenylphosphine)ruthenium(ll) and 160.0 mg (0.296 mmol) of ligand L2 are placed in a 10 ml Schlenk tube and admixed with 6.5 ml of dry toluene under argon. The dark suspension is stirred overnight at room temperature, resulting in a colour change to orange-red. After addition of 4 ml of dry pentane, the stirrer is switched off and the supernatant orange solution is filtered off with suction from the orange solid. The solid is washed five times with 4 ml each time of pentane and dried in a high vacuum. This gives 244 mg (88% of theory) of the title compound as an orange powder. 31P-NMR (C6D6, 121.5 MHz, ppm): 49.7 (d, J = 40), 61.2 (d, J = 40).

As the paragraph descriping shows that 15529-49-4 is playing an increasingly important role.

Reference£º
Patent; SOLVIAS AG; WO2007/104690; (2007); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.246047-72-3,(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium,as a common compound, the synthetic route is as follows.

Grubbs second generation catalyst (100 mg, 0.117 mmol), 2-[(2,6-dimethylphenylimino)methyl]phenol (pKa: 8.85+/- 0.30) (0.117 mmol), silver (I) carbonate (16.27 mg, 0.058 mmol), and THF (2 ml) were reacted at room temperature during 2 h. The solvent was evaporated and crude reaction product purified on a chromatography column to give an orange-brown complex. Yield 22%.

246047-72-3 (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 11147261, aruthenium-catalysts compound, is more and more widely used in various.

Reference£º
Patent; Telene SAS; EP2151446; (2010); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

With the rapid development and complex challenges of chemical substances, new drug synthesis pathways are usually the most effective.246047-72-3,(1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium,as a common compound, the synthetic route is as follows.

To a 40 mL scintillation vial equipped with a magnetic stir bar were added C848 (0.500 g, 0.589 mmol),^-toluenesulfonyl chloride (0.056 g, 0.30 mmol), dimethyl sulfoxide (0.230 g, 2.94 mmol), and dichloromethane (4 mL). The reaction was stirred at ambient temperature for one hour then filtered through a plug of celite and combined with diethyl ether (30 mL). The resulting purple precipitate was isolated by filtration, washed with diethyl ether (2 x 10 mL) then dried in vacuum to afford C647m as a purple crystalline solid (0.269 g, 70.7% yield). The X-ray structure of C647m is shown in Figure 2. MR (400 MHz, CeDe) delta 16.03 (s, 1H), 8.15 (d, J = 25.0 Hz, 2H), 7.21 (t, J = 7.3 Hz, 1H), 7.00 (t, J= 7.8 Hz, 2H), 6.84 (s, 1H), 6.75 (s, 1H), 6.65 (s, 1H), 6.17 (s, 1H), 3.33 – 3.00 (m, 4H), 2.87 (s, 3H), 2.67 (s, 3H), 2.61 (s, 3H), 2.22 (s, 3H), 2.14 (s, 3H), 2.07 (s, 3H), 2.04 (s, 3H), 1.98 (s, 3H).

246047-72-3 (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium 11147261, aruthenium-catalysts compound, is more and more widely used in various.

Reference£º
Patent; MATERIA, INC.; JOHNS, Adam, M.; (112 pag.)WO2018/38928; (2018); A1;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

246047-72-3, (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

After a 50 mL two-necked flask was purged with argon, the ligand 7t (10 mmol), 30 mL of CuCl (30 mmol, 3 eq) and 30 mL of dry DCM were sequentially added and the mixture was purged three times with argon to protect the closed system with argon balloon. Ruthenium complex 1b (12 mmol) was added under argon atmosphere, and the reaction was carried out at room temperature for 0.5 hour. After the reaction was over, silica gel was added to the filtrate to produce sand after filtration. The crude product was obtained by silica gel column chromatography, and then washed with methanol or pentane-DCM to obtain 8t as a green solid product in a yield of 87%.

The synthetic route of 246047-72-3 has been constantly updated, and we look forward to future research findings.

Reference£º
Patent; Zannan Science And Technology (Shanghai) Co., Ltd.; Zhan Zhengyun; (102 pag.)CN104262403; (2017); B;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

15529-49-4, Dichlorotris(triphenylphosphino)ruthenium (II) is a ruthenium-catalysts compound, ?involved in a variety of chemical synthesis. Rlated chemical reaction is continuously updated

General procedure: The same basic method, as described here for [RuCl(PPh3)2(LMe,H)]Cl, was followed for all the complexes in this study. Asuspension of [RuCl2(PPh3)3] (0.36 g, 0.4 mmol) and LMe,H (0.15 g,0.4 mmol) in dry dichloromethane (15 cm3) was stirred for 3 h atroom temperature. This yielded an orange precipitate, which wascollected by filtration. Alternatively, the products 3-6 were solublein the reaction mixture, and were precipitated from it by careful addition of diethyl ether. In either case, the resultant solids werewashed repeatedly with diethyl ether to remove excess PPh3, thendried in vacuo.

The synthetic route of 15529-49-4 has been constantly updated, and we look forward to future research findings.

Reference£º
Article; Roberts, Thomas D.; Halcrow, Malcolm A.; Polyhedron; vol. 103; (2016); p. 79 – 86;,
Highly efficient and robust molecular ruthenium catalysts for water oxidation
Catalysts | Special Issue : Ruthenium Catalysts – MDPI