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Conventional reactions of trans-Ru(CCCCH)2(dppe)2 1 with RuCl(PP)Cp? or AuCl(PPh3) have given the complexes trans-Ru(CCCCR)(CCCCR?)(dppe)2 [R = H, Ru(PP)Cp?, Au(PPh3); R? = Ru(PP)Cp?, (PP)Cp? = (PPh 3)2Cp, (dppe)Cp, (dppe)Cp (not all combinations)]. The Au(PPh3) derivatives react with Co(mu3-CBr)(mu-dppm) (CO)7 to give trans-Ru(CCCCH){CCCCC[Co3(mu-dppm)(CO) 7]}(dppe)2 and trans-Ru{CCCCC[Co3(mu-dppm) (CO)7]}2(dppe)2, which contain respectively four- and five-carbon and two five-carbon chains linking the metal centres. Also described is the addition of tcne to trans-Ru(CCCCH)2(dppe) 2 to give the bis(eta1-tetracyanobutadienyl) complex trans-Ru{CCC[C(CN)2]CHC(CN)2}2(dppe) 2 11, of which the single crystal X-ray structure is reported.
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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI