Some scientific research about Ruthenium(III) chloride

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Fluphenazine hyrochloride (FPH) and triflupromazine hyrochloride (TPH) form red coloured species with ruthenium(III) instantaneously at room temp. in hydrochloric acid medium.The absorption maximum and molar absorptivity of the red coloured species are 500 nm and 6.4E3 litre mole-1 cm-1 for FPH, and 510 nm and 6.3E3 litre mole-1 cm-1 for TPH.Beer’s law is valid over the concentration range 0.2-11.52 ppm of ruthenium(III) for FPH, and 0.5-9 ppm of ruthenium(III) for RPH.The proposed methods offer the adventages of simplicity, sensitivity, stability and rapidity without the need for extraction.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Awesome and Easy Science Experiments about Ruthenium(III) chloride

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The X-ray structure of the potential antitumour complex trans- [RuCl3(H2O)(admtp)2] · H2O (admtp = 2-amino-5,7- dimethyl[1,2,4]triazolo[1,5-a]pyrimidine) shows unique and very interesting intramolecular hydrogen-bonding properties with the non-bridgehead pyrimidinic nitrogen atom of admtp acting as hydrogen acceptor and the amino group acting as hydrogen donor.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

A new application about Ruthenium(III) chloride

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: Cl3Ru. In my other articles, you can also check out more blogs about 10049-08-8

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Ternary platinum-ruthenium-nickel nanoparticles are prepared by water-in-oil reverse microemulsions of water/Triton X-100/propanol-2/cyclohexane. Nanoparticles formed in the microemulsions are characterized by transmission electron microscopy (TEM), electron diffraction (ED), X-ray diffractometry (XRD), energy dispersive X-ray analysis (EDX). These resulting materials showed a homogenous alloy structure, the mono-dispersion and an average diameter of 2.6 ± 0.3 nm with a narrow particle size distribution. The composition and particle size of ternary Pt-Ru-Ni nanoparticles can be controlled by adjusting the initial metal salt solution and preparation conditions. Pt-Ru-Ni ternary metallic nanoparticles showed an enhanced catalytic activity towards methanol oxidation compared to Pt-Ru bimetallic nanoparticles.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

New explortion of Ruthenium(III) chloride

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The recyclability of water-soluble ruthenium-phosphine complex catalysts was investigated in water-toluene and in water-pressurized carbon dioxide systems for selective hydrogenation of trans-cinnamaldehyde (CAL). For the first hydrogenation run, the selectivity for cinnamyl alcohol (COL) is high for both toluene and dense CO2, because of interfacial catalysis in which the reaction mainly occurs at the interface between the aqueous phase and the other toluene or dense CO2 phase. The total CAL conversion and the COL selectivity decrease on the second run, more significantly with dense CO2 than toluene. On the subsequent runs, however, less significant changes were observed. During the first run, the active metal complexes should change to much less active ones such as Ru(H)2Ln(TPPTS)m (L = COL) by accumulation of the main product of COL. This structural change may occur more easily in multiphase hydrogenation with dense CO2 than that with toluene, probably because the solubility in the dense CO2 gas phase is even smaller than that in toluene. For homogeneous reaction of COL in aqueous phase, Ru(H)2Ln(TPPTS)m catalyzes the isomerization to HCAL compared with the hydrogenation to hydrocinnamyl alcohol. With those complexes, however, the selectivity for COL is still comparable to that for HCAL for multiphase hydrogenation reactions because the hydrogenation of an ampholytic substrate of CAL occurs mainly at interface between water and toluene or dense CO2 gas phase. Interactions of CO2 molecules with CAL would also increase the reactivity of carbonyl group of the substrate.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

The important role of Ruthenium(III) chloride

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A series of new complexes with mixed ligands of the type RuL m (DMSO) n Cl3?xH2O ((1) L: oxolinic acid (oxo), m = 1, n = 0, x = 4; (2) L: pipemidic acid (pip), m = 2, n = 1, x = 2; (3) L: enoxacin (enx), m = 2, n = 1, x = 0; (4) L: levofloxacin (levofx), m = 2, n = 2, x = 8; DMSO: dimethylsulfoxide) were synthesized and characterized by chemical analysis, IR and electronic data. Except oxolinic acid that behaves as bidentate, the other ligands (quinolone derivatives and DMSO) act as unidentate. Electronic spectra are in accordance with an octahedral stereochemistry. The thermal analysis (TG, DTA) in synthetic air flow elucidated the composition and also the number and nature of both water and DMSO molecules. The TG curves show 3-5 well-separated thermal steps. The first corresponds to the water and/or DMSO loss at lower temperatures followed either by quinolone thermal decomposition or pyrolisys at higher temperatures. The final product is ruthenium(IV) oxide.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Some scientific research about Ruthenium(III) chloride

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This paper embodies the first report on the electrochemical deposition of RuS2 thin films. The as-deposited and heat-treated films (in argon atmosphere) were characterized by XRD, SEM and UV-VIS-NIR spectrophotometry. The polycrystalline deposits of RuS2 obtained indicated a cubic structure with a lattice constant of 5.685 angstroms, an average grain size around 3 mum, and an absorption coefficient of 5×104 cm-1. The optical band gap was found to be 1.48 eV.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Discovery of Ruthenium(III) chloride

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Electron spectroscopy chemical analysis was carried out with X-ray excitation (XPS). An alternative attribution for the observed optical transitions is suggested.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Archives for Chemistry Experiments of Ruthenium(III) chloride

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The disulphide diamide SRR-SB3 (7-methyl-6,7,8,9-tetrahydrodibenzo [c,k] [1,2,6,9] dithiadiazacyclododecine-5-10-dione) and its metal complexes have been synthesized and characterised by elemental analyses, IR, 1H{ 13C} NMR, mass spectra and magnetic moment data. The complexation of the ligand SRR-SB3 with several metal ions such as ruthenium(III), cobalt(II), iron(III), lead(II), copper(II), nickel(II), zinc(II), manganese(II) and palladium(II) chloride have been studied. The metal ions, Ru and Zn are found to complex successfully with SRR-SB3. The metal complexes have been found to inhibit the replication of HIV-1 (IIIB) and HIV-2 (ROD) strains using MT-4 cells with a selectivity index ranging from 5 to 27.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

New explortion of Ruthenium(III) chloride

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Formula: Cl3Ru. In my other articles, you can also check out more blogs about 10049-08-8

10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 10049-08-8, Safety of Ruthenium(III) chloride

Pt and Pt-Ru alloys with several Pt/Ru ratios supported on carbon (Vulcan) were prepared using high-intensity ultrasound by reduction of H2PtCl6 and RuCl3 precursors in an aqueous solution. This method of catalyst preparation was performed in absence of any surfactant or organic addictive. The particles formed were characterized by X-ray diffraction (XRD), energy dispersive X-ray (EDX) and transmission electron microscopy (TEM). From the XRD studies, a decrease of metal particle size and of the lattice parameters was observed with the increase of the Ru content. The electroactivities were tested for the methanol oxidation reaction in acid electrolyte, and it was found that Pt-Ru catalysts were more activity than pure Pt.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI

Archives for Chemistry Experiments of Ruthenium(III) chloride

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 10049-08-8, help many people in the next few years., Electric Literature of 10049-08-8

Related Products of 10049-08-8, An article , which mentions 10049-08-8, molecular formula is Cl3Ru. The compound – Ruthenium(III) chloride played an important role in people’s production and life.

The disulphide diamide SRR-SB3 (7-methyl-6,7,8,9-tetrahydrodibenzo [c,k] [1,2,6,9] dithiadiazacyclododecine-5-10-dione) and its metal complexes have been synthesized and characterised by elemental analyses, IR, 1H{ 13C} NMR, mass spectra and magnetic moment data. The complexation of the ligand SRR-SB3 with several metal ions such as ruthenium(III), cobalt(II), iron(III), lead(II), copper(II), nickel(II), zinc(II), manganese(II) and palladium(II) chloride have been studied. The metal ions, Ru and Zn are found to complex successfully with SRR-SB3. The metal complexes have been found to inhibit the replication of HIV-1 (IIIB) and HIV-2 (ROD) strains using MT-4 cells with a selectivity index ranging from 5 to 27.

I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 10049-08-8, help many people in the next few years., Electric Literature of 10049-08-8

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI