Do you like my blog? If you like, you can also browse other articles about this kind. 32993-05-8Thanks for taking the time to read the blog about 32993-05-8
In an article, published in an article,authors is Ashok, R. F. N., once mentioned the application of 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II),molecular formula is C41H35ClP2Ru, is a conventional compound. this article was the specific content is as follows.32993-05-8
Cyclopentadienyl ruthenium complexes. Part III. Reactivity of some eta5-cyclopentadienylbis(triphenylphosphine)ruthenium(II) complexes with nitrosyl tribromide and dinitrogen trioxide
Mixed ruthenium(II) nitrosyls have been synthesized in yields larger than 60percent by a general reaction of +X- (L = 2,2′-bipyridine or 1,10-phenanthroline, X- = Cl- or Br-) or (L = PPh3, pyridine, 3-picoline, 4-picoline, 1/2(2,2′-bipyridine), or 1/2(1,10-phenanthroline); X- = Cl-, Br-, I-, CN-, NCS-, H-, or SnCl3-) with NOBr3 and N2O3.In these complexes NO seems to bind with the metal ion as NO+.The reactions of N2O3 gave either nitrito or nitrosyl dinitrito complexes.The reactions of NOBr3 with trichlorostannate complexes did not yield nitrosyl complexes, instead nitrito complexes were isolated in which spectroscopic evidence (ir, 1H nmr) suggest ?-interaction of one of the phenyl rings of the triphenylphosphine ligand to the ruthenium center.All products are characterised by elementary microanalyses, conductivity, magnetic moment measurements, electronic, ir, 1H nmr spectral data.
Do you like my blog? If you like, you can also browse other articles about this kind. 32993-05-8Thanks for taking the time to read the blog about 32993-05-8
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI