32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.
Syntheses, structures, some reactions, and electrochemical oxidation of ferrocenylethynyl complexes of iron, ruthenium, and osmium
The syntheses and characterizations of several complexes containing ferrocenylethynyl and ferrocene-1,1?-bis(ethynyl) groups attached to M(PP)Cp? [M = Fe, Ru, PP = dppe, Cp? = Cp*; M = Ru, Os, PP = (PPh3)2, dppe, Cp? = Cp] are described. Reactions with tetracyanoethene have given either tetracyanobuta-1,3-dienyl or eta3-allylic derivatives, while addition of Me+ afforded the corresponding vinylidene derivatives. Some electrochemical measurements are discussed in terms of electronic communication between the redox-active M(PP)-Cp? groups through the ferrocene nucleus. The molecular structures of 14 of these complexes have been determined by crystallographic methods.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI