The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about Catalytic Oxidative Cleavage Reactions of Arylalkenes by tert-Butyl Hydroperoxide – A Mechanistic Assessment, the main research direction is arylalkene catalytic oxidative cleavage reaction mechanism tert butyl hydroperoxide.Application In Synthesis of Dirhodium(II) tetrakis(caprolactam).
Oxidative cleavage reactions of arylalkenes by tert-Bu hydroperoxide that occur by free radical processes provide access to carboxylic acid or ketone products. However, the pathway to these cleavage products is complex, initiated by regioselective oxygen radical addition to the carbon-carbon double bond. Subsequent reactions of the initially formed benzyl radical lead eventually to carbon-carbon cleavage. Thorough investigations of these reactions have identified numerous reaction intermediates that are on the pathways to final product formation, and they have identified a new synthetic methodol. for the synthesis of peroxy radical addition-induced hydroperoxide formation.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI