Application of 15418-29-8. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Structurally Precise Silver Sulfide Nanoclusters Protected by Rhodium(III) Octahedra with Aminothiolates. Author is Ueda, Misaki; Goo, Zi Lang; Minami, Katsue; Yoshinari, Nobuto; Konno, Takumi.
A 60-nuclear silver sulfide nanocluster with a highly pos. charge (1) has been synthesized by mixing an octahedral RhIII complex with 2-aminoethanethiolate ligands, silver(I) nitrate, and D-penicillamine in water under mild conditions. The spherical surface of 1 is protected by the chiral octahedral RhIII complex, with cleavage of the C-S bond of the D-penicillamine supplying the sulfide ions. Although 1 does not contain D-penicillamine, it is optically active because of the enantiomeric excess of the RhIII mols. induced by chiral transfer from D-penicillamine. 1 Can accommodate/release external Ag+ ions and replace inner Ag+ ions by Cu+ ions. The study demonstrates that a thiolato metal complex and sulfur-containing amino acid can be used as cluster-surface-protecting and sulfide-supplying regents, resp., for creating chiral, water-soluble, structurally precise silver sulfide nanoclusters, the properties of which are tunable through the addition/removal/exchange of Ag+ ions.
This literature about this compound(15418-29-8)Application of 15418-29-8has given us a lot of inspiration, and I hope that the research on this compound(Copper(I) tetra(acetonitrile) tetrafluoroborate) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI