Synthetic Route of C24H40N4O4Rh2. Aromatic compounds can be divided into two categories: single heterocycles and fused heterocycles. Compound: Dirhodium(II) tetrakis(caprolactam), is researched, Molecular C24H40N4O4Rh2, CAS is 138984-26-6, about Intramolecular C-H insertion using NHC-di-rhodium(II) complexes: the influence of axial coordination. Author is Gomes, Luis F. R.; Trindade, Alexandre F.; Candeias, Nuno R.; Gois, Pedro M. P.; Afonso, Carlos A. M..
In this work we show that the intramol. C-H insertion of diazoacetamides catalyzed by dirhodium(II) complexes can be highly influenced by the axial ligand on the di-rhodium(II) complex. Axially monocoordinated NHC-Rh2(OAc)4 complexes have a distinct reactivity from the parent Rh2(OAc)4 complex affording the cyclization products in different rates and selectivities. Surprisingly, a new reaction mode emerged when using these complexes which led to a decarbonylation pathway.
This literature about this compound(138984-26-6)Synthetic Route of C24H40N4O4Rh2has given us a lot of inspiration, and I hope that the research on this compound(Dirhodium(II) tetrakis(caprolactam)) can be further advanced. Maybe we can get more compounds in a similar way.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI