Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 60804-74-2, is researched, SMILESS is F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.C1(C2=NC=CC=C2)=NC=CC=C1.C3(C4=NC=CC=C4)=NC=CC=C3.C5(C6=NC=CC=C6)=NC=CC=C5.[Ru+2], Molecular C30H24F12N6P2RuJournal, Journal of Industrial and Engineering Chemistry (Amsterdam, Netherlands) called Mechanically robust and thermally stable electrochemical devices based on star-shaped random copolymer gel-electrolytes, Author is Hwang, Heedong; Lee, Jaeyong; Park, So Yeong; Seo, Yeseong; Kim, Yong Min; Kim, Jin Kon; Moon, Hong Chul, the main research direction is polystyrene polymethylmethacrylate star shaped random copolymer viscoelastic property.Application of 60804-74-2.
We synthesized 6-arm star-shaped polystyrene-ran-poly(Me methacrylate) copolymers ((S-r-M)6) for mech. robust and thermally stable ion gels containing an ionic liquid of 1-ethyl-3-methylimidazolium bis(trifluoromethyl sulfonyl)imide ([EMI][TFSI]). The (S-r-M)6-based gels exhibited higher elastic modulus (E ∼ 1.67 x 105 Pa), which is more than five-times that (∼0.29 x 105 Pa) of linear PS-r-PMMA-based ion gels at the same Sty content (∼29 mol%), irresp. of applied mech. strains (stretching and compression). In addition, they showed outstanding thermal stability. For example, the gel-sol transition temperature (Tgel) of (S-r-M)6 gels was ∼72 °C, compared with that (∼56 °C) of linear PS-r-PMMA-based ion gels. These phys. properties of gels were further improved by increasing total mol. weight and the fraction of styrene, giving E of ∼3.8 x 105 Pa and Tgel of ∼163 °C. The resulting gels were functionalized by introducing electrochemiluminescence luminophores (tris(2,2′-bipyridyl)ruthenium(II) hexafluorophosphate). By utilizing the mech. robustness of the (S-r-M)6 gels, we fabricated emissive electrochem. displays through ′cut-and-stick′ process. Moreover, the thermally stable (S-r-M)6 gels indicated good dimensional stability, offering a chance to demonstrate ECL devices that operate even at high temperatures
In addition to the literature in the link below, there is a lot of literature about this compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate))Application of 60804-74-2, illustrating the importance and wide applicability of this compound(60804-74-2).
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI