Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate), is researched, Molecular C30H24F12N6P2Ru, CAS is 60804-74-2, about Aryl Sulfonium Salts for Site-Selective Late-Stage Trifluoromethylation.Application In Synthesis of Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate).
Incorporation of the CF3 group into arenes has found increasing importance in drug discovery. Herein, we report the first photoredox-catalyzed cross-coupling of aryl thianthrenium salts with a copper-based trifluoromethyl reagent, which enables a site-selective late-stage trifluoromethylation of arenes. The reaction proceeds with broad functional group tolerance, even for complex small mols. on gram scale. The method was further extended to produce pentafluoroethylated derivatives
I hope my short article helps more people learn about this compound(Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate))Application In Synthesis of Tris(2,2′-bipyridine)ruthenium bis(hexafluorophosphate). Apart from the compound(60804-74-2), you can read my other articles to know other related compounds.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI