Synthetic Route of C8H12BCuF4N4. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Synthesis of an N, N-diethyl-tert-butylazothioformamide ligand and coordination studies with Copper(I) salts.
Redox-active azothioformamides ligands rapidly coordinate to transition metals and are excellent substrates for monitoring host-guest binding interaction mechanisms as they can exhibit unique coordination complexes while producing an increase in extinction coefficient upon addition of metal salt. Herein, an alkyl derivative, N,N-diethyl-t-butylazothioformamide, was synthesized and fully characterized, including x-ray crystallog. Crystalline coordination complexes were prepared with various copper(I) salts (CuBr, CuI and [(MeCN)4Cu]BF4) producing both 1:1μ-X dimers from copper(I) halides and a distorted tetrahedral 2:1 species with non-coordinative tetrafluoroborate salt. Bond distances and angles suggest neutrally bound alkyl azothioformamide ligands with copper(I), indicating no redox activity upon binding. UV-visible titration studies with copper(I) salts and subsequent data evaluation with both 1:1 and 2:1 non-linear regression binding models suggest inconsistent mechanisms with copper(I) salts.
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