Mosnacek, Jaroslav; Kundys, Anna; Andicsova, Anita published the article 《Reversible-deactivation radical polymerization of methyl methacrylate induced by photochemical reduction of various copper catalysts》. Keywords: methyl methacrylate copper catalyst atom transfer radical photo polymerization; UV visible light living controlled polymerization photochem reduction.They researched the compound: 2-Bromopropanenitrile( cas:19481-82-4 ).Synthetic Route of C3H4BrN. Aromatic heterocyclic compounds can be divided into two categories: single heterocyclic and fused heterocyclic. In addition, there is a lot of other information about this compound (cas:19481-82-4) here.
Photochem. mediated reversible-deactivation radical polymerization of Me methacrylate was successfully performed using 50-400 ppm of various copper compounds such as CuSO4.5H2O, copper acetate, copper triflate and copper acetylacetonate as catalysts. The copper catalysts were reduced in situ by irradiation at wavelengths of 366-546 nm, without using any addnl. reducing agent. Bromopropionitrile was used as an initiator. The effects of various solvents and the concentration and structure of ligands were investigated. Well-defined polymers were obtained when at least 100 or 200 ppm of any catalyst complexed with excess tris(2-pyridylmethyl)amine as a ligand was used in DMSO as a solvent.
There is still a lot of research devoted to this compound(SMILES：CC(Br)C#N)Synthetic Route of C3H4BrN, and with the development of science, more effects of this compound(19481-82-4) can be discovered.
Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI