Johnson, Alice; Gimeno, M. Concepcion published an article about the compound: Copper(I) tetra(acetonitrile) tetrafluoroborate( cas:15418-29-8,SMILESS:[Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-] ).Application of 15418-29-8. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:15418-29-8) through the article.
Yldiides have unique electronic properties and donor abilities, but as ligands in transition metal complexes they are scarcely represented in the literature. Here, the controlled synthesis of a series of polynuclear gold yldiide complexes derived from triphenyl(cyanomethyl)phosphonium bromide, [Ph3PCH2CN]Br, under mild conditions is described. Anionic dinuclear NBu4[(AuX)2{C(CN)PPh3}] (X = Cl, C6F5) or trinuclear derivatives NBu4[Au3X2{C(CN)PPh3}] bearing terminal chloride or pentafluorophenyl groups and bridging yldiide ligands have been prepared These compounds evolve in solution giving rise to the formation of an unprecedented tetrameric gold cluster, [Au4{C(CN)PPh3}4], by the loss of the gold complex NBu4[AuX2]. This gold cluster can also be prepared in high yield by a transmetalation reaction from the analogous tetrameric silver cluster, and two geometric isomers have been characterized, their formation dependent on the synthetic route. The triphenylphosphonium cyanomethyldiide ligand has also been used to build different dinuclear and trinuclear cationic complexes bearing phosphine or diphosphine ancillary ligands and bridging yldiide moieties. Further coordination through the cyano group of the yldiide ligand gives heterometallic trinuclear or pentanuclear derivatives Structural characterization of many of these compounds reveals the presence of complex mol. systems stabilized by gold···gold interactions and bridging yldiide ligands.
There is still a lot of research devoted to this compound(SMILES：[Cu+](N#CC)(N#CC)(N#CC)N#CC.[B+3]([F-])([F-])([F-])[F-])Application of 15418-29-8, and with the development of science, more effects of this compound(15418-29-8) can be discovered.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI