The important role of 376581-24-7

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Ye, Liu; Gu, Qiang-Shuai; Tian, Yu; Meng, Xiang; Chen, Guo-Cong; Liu, Xin-Yuan published an article about the compound: Quinolin-6-ylboronic acid( cas:376581-24-7,SMILESS:OB(C1=CC=C2N=CC=CC2=C1)O ).Related Products of 376581-24-7. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:376581-24-7) through the article.

An intramol. radical cyclopropanation of unactivated alkenes with simple α-methylene group of aldehydes as C1 source via a Cu(I)/secondary amine cooperative catalyst, which enabled the single-step construction of bicyclo[3.1.0]hexane skeletons with excellent efficiency, broad substrate scope covering various terminal, internal alkenes as well as diverse (hetero)aromatic, alkenyl, alkyl-substituted geminal alkenes was reported. Moreover, this reaction was successfully realized to an asym. transformation, providing an attractive approach for the construction of enantioenriched bicyclo[3.1.0]hexanes bearing two crucial vicinal all-carbon quaternary stereocenters with good to excellent enantioselectivity. The utility of this method was illustrated by facile transformations of the products into various useful chiral synthetic intermediates. Preliminary mechanistic studies supported a stepwise radical process for this formal [2+1] cycloaddition

There is still a lot of research devoted to this compound(SMILES:OB(C1=CC=C2N=CC=CC2=C1)O)Related Products of 376581-24-7, and with the development of science, more effects of this compound(376581-24-7) can be discovered.

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI