Recommanded Product: Copper(I) tetra(acetonitrile) tetrafluoroborate. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Copper(I) complex with BINAP and 3,5-dimethylpyrazole: synthesis and photoluminescent properties.
A reaction of [Cu(MeCN)4]BF4 with PzH (3,5-dimethylpyrazole) and BINAP [2,20-bis(diphenylphosphino)-1,10-binaphthyl] gives mononuclear CuI complex [Cu(PzH)(BINAP)]BF4 containing the mol. of nondeprotonated pyrazole and one BINAP ligand with two phosphorus atoms chelating the metal. This complex exhibits a bright phosphorescence originating from the 3(M+L)LCT state at room temperature At 77 K, the emission is splitted into two components: 3(M+L)LCT and 3LC transitions.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI