Reference of Copper(I) tetra(acetonitrile) tetrafluoroborate. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Copper(I) tetra(acetonitrile) tetrafluoroborate, is researched, Molecular C8H12BCuF4N4, CAS is 15418-29-8, about Binuclear Cu(I) and Mn(0) Complexes with a Tridentate Pyridine-NHC-Phosphane Ligand in a μ-κ2C,̂N-M;κ1P-M Coordination Mode. Author is Willot, Jeremy; Lugan, Noel; Valyaev, Dmitry A..
The reaction of a non-sym. pyridine-NHC-phosphine (NCP̂) ligand – generated in situ upon the deprotonation of the corresponding imidazolium salt – with equimolar amount of [Cu(NCMe)4](BF4) or Mn2(CO)10 leads to the formation of bimetallic complexes [Cu2(NCP̂)2(NCMe)](BF4)2 and [Mn2(CO)7(NCP̂)], resp., in which the tridentate ligand exhibits an unusual μ-κ2C,̂N-M;κ1P-M coordination mode. According to NMR spectroscopy and mass spectrometry, the binuclear copper complex is in equilibrium in MeCN solution with two mononuclear species, namely [Cu(κ2C,̂P-NCP̂)2](BF4) and [Cu(κ3-N,C,̂P-NCP̂)(NCMe)](BF4).
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