22-Sep News Awesome and Easy Science Experiments about Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Related Products of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

Several ruthenium complexes of the CpRuX(PPh3)2 type, where X=Cl, Br, I, NCS, NCO, CN, BH4, H, D, and some of the CpRuS2CZ(PPh3) type, where Z=NR2 or OR, were obtained.The hydride CpRuH(PPh3)2 was obtained in high yield by reaction of CpRuCl(PPh3)2 with ROM (R=alkyl, M=alkali metal).The other complexes were obtained by ligand exchange of the chloride or hydride with MX salts or HX acids, respectively.Reaction of chloride or hydride with cyclopentadiene led to ruthenocene.However, when pyrrole was used instead of cyclopentadiene, it was not possible to obtain azaruthenocene in this way.

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Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI