In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C12H12Cl4Ru2
The cationic complexes [(eta6-arene)Ru(SC5H4NH)3]2+, arene being C6H6 (1), MeC6H5 (2), p-iPrC6H4Me (3) or C6Me6 (4), have been synthesised from the reaction of 4-pyridinethiol with the corresponding precursor (eta6-arene)2Ru2(mu2-Cl)2Cl2 and isolated as the chloride salts. The single-crystal X-ray structure of [4](PF6)2 reveals three 4-pyridinethiol moieties coordinated to the ruthenium centre through the sulphur atom, with the hydrogen atom transferred from the sulphur to the nitrogen atom. The electrochemical study of 1-4 shows a clear correlation between the Ru(II)/Ru(III) redox potentials and the number of alkyl substituents at the arene ligand (E? (RuII/III): 1 > 2 > 3 > 4), whereas the cytotoxicity towards A2780 ovarian cancer cells follows the series 4 > 1 > 3 > 2, the hexamethylbenzene derivative 4 being the most cytotoxic one. The corresponding reaction of the ortho-isomer, 2-pyridinethiol, with (eta6-C6Me6)2Ru2(mu2-Cl)2Cl2 does not lead to the expected 2-pyridinethiolato analogue, but yields the neutral complex (eta6-C6Me6)Ru(eta2-SC5H4N)(eta1-SC5H4N) (5). The analogous complex (eta6-C6Me6)Ru(eta2-SC9H6N)-(eta1-SC9H6N) (6) is obtained from the similar reaction with 2-quinolinethiol.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI