Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery., Application In Synthesis of Dichloro(benzene)ruthenium(II) dimer
The synthesis and structural characterization of the family of the cubane-like complexes [(eta6-C6H6)Ru(OH)4[OH] 4·12H2O (1), [(eta6-C6H6)Ru(OH)]4[BF 4]3[Cl]·2H2O (2), and [(eta6-C6H6)3-Ru 4(OH)4(Cl)3][BF4] 2·3H2O (3) are reported. The relationship between molecular and crystal structure of the complexes has been investigated by means of theoretical calculations of the DFT type. In the solid state, compound 1 shows the presence of benzene-benzene contacts between perfectly eclipsed ligands belonging to neighboring molecules. These are surrounded by a “belt” of water molecules forming C-H…O hydrogen bonds with the coordinated benzene. These H-bonds would appear to be sufficiently strong to compensate the anticipated repulsive benzene-benzene interactions. The role of (M-)Cl…H-O and Cl-…H-O interactions in 2 and 3 has also been investigated.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI