A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Patent，once mentioned of 10049-08-8, Recommanded Product: Ruthenium(III) chloride
A process has been invented for the oxygenation of cyclic ethers. General problems in the process are the use of expensive and toxic oxidants, low TONs (turnover numbers), low selectivity and working at elevated temperatures (energy costs). These problems were solved by employing appropriate organometallic catalyst precursors. Using lnd(CO)3Mo-Ru(CO)2Cp, Cp(CO)3Mo-Ru(CO)2Cp and Cp(CO)2Ru-Ru(CO)2Cp or other ruthenium compounds, the aerobic oxidation of tetrahydrofurane (THF) proceeds at room temperature and produces selectively gamma-butyrolactone. Use of the catalysts yields replacement of stoichiometric, toxic co-oxidants by cheap air oxygen, working at room temperature, high selectivity, high TONs and overall formulation of green chemistry which is applicable to cyclic ethers: formula (I) The invented process satisfies the urge for green chemistry by using cheap air oxygen in a catalytic process with unlimited catalyst lifetime and plain water as the side product. Functionalised lactones will be available from corresponding ethers.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.HPLC of Formula: Cl3Ru, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 10049-08-8, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI