Application of 32993-05-8. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)
The mononuclear chelated complex [RuCl(Cp)(eta2-dppa)] has been synthesised and reacted with [Rh2Cl2(CO)4] to form the heterobimetallic complex [(Cp)Ru(mu-CO)2{(mu-Ph2PN(H)PPh2}RhCl 2]. Complexes of [RuCl(Cp){(PPh2)2CHCH2PPh2}] have been reacted with [Rh2Cl2(CO)4] or [RhCl(CO)2(p-toluidene)]. Characterisation of these new ruthenium complexes was carried out using 31P-NMR, FAB mass spectroscopy, elemental analysis and IR spectrophotometry.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI