In an article, published in an article, once mentioned the application of 172222-30-9, Name is Benzylidenebis(tricyclohexylphosphine)dichlororuthenium,molecular formula is C43H72Cl2P2Ru, is a conventional compound. this article was the specific content is as follows.Formula: C43H72Cl2P2Ru
A sixteen-step synthesis of the twelve-membered macrolide (-)-cladospolide B (2) from the microbially-derived cis-1,2-dihydrocatechol 5 is described. Pivotal steps include the ring-closing metathesis (RCM) of diene 12 to give the ten-membered lactone 13 together with small amounts of the head-to-tail and head-to-head dimers 14 and 15, respectively. The saturated lactol 19 derived from compounds 13 and 14 readily participates in a Wadsworth-Horner-Emmons reaction to give the E-configured alpha,beta-unsaturated ester 20. This last compound is then converted, through application of a Yamaguchi lactonisation reaction on the derived acid 22, into the macrolide 23 which, upon removal of the bis-acetal protecting group, affords compound 24, the E-isomer of target 2. Irradiation of a benzene solution of compound 24 results in its partial photoisomerisation to (-)-cladospolide B (2). The Royal Society of Chemistry 2005.
Do you like my blog? If you like, you can also browse other articles about this kind. Formula: C43H72Cl2P2Ru. Thanks for taking the time to read the blog about 172222-30-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI