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Tetradentate and ambidentate: Because the four-atom acetylenedithiolate has donor electron density on all sides of the dianion, it can link and electronically couple different metal ions. The bend-back angles of the sulfur atoms in the eta2-C,C?-acetylenedithiolate complex [Tp?W(CO)2(eta2-C2S2)] – are sufficiently flexible to allow for a chelation of both sulfur donors to the {(eta5-C5H5)Ru(PPh 3)} fragment (see structure). (Chemical Equation Presented).
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI