Related Products of 37366-09-9. Chemistry is an experimental science, and the best way to enjoy it and learn about it is performing experiments.Introducing a new discovery about 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer
Norbomene as well as its 5,6-disubstituted derivatives and oxa- norbornene undergoes a novel cyclopropanation with propargyl alcohol in methanol containing cationic (eta5- cyclopentadienyl)tris(acetonitrile)ruthenium complexes as catalysts to give exo-3-acetyltricyclooctane derivatives. Cyclopentadienylruthenium catalysts having an electron-withdrawing substituent on the Cp ligand exhibited the highest activity and the cyclopropanation proceeded even at -20 C. On the basis of a deuterium labeling experiment, a reaction mechanism involving a ruthenacycle intermediate is proposed.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI