The reaction rate of a catalyzed reaction is faster than the reaction rate of the uncatalyzed reaction at the same temperature.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a Article，once mentioned of 32993-05-8, HPLC of Formula: C41H35ClP2Ru
Substitution of PPh3 in [RuCp(PPh3)2Cl] with highly basic PMe3 gave a remarkable change in the reactivity towards P4 and unexpectedly only the bimetallic complex cation [{RuCp(PMe3)2}2(mu,eta1:1-P4)]2+ (3) was formed which was characterized by NMR spectroscopy and single crystal X-ray diffraction analysis. The equimolar reaction between the synthon [RuCp(PMe3)2]+ and the mixed cage P4S3 is highly selective quantitatively yielding only the product with eta1-Pbasal coordination to ruthenium. On the other hand, the related [RuCp(PPh3)2]+ cation gave a 2:1 mixture of mono-eta1-Pbasal and bimetallic complex. The solid state structure of [RuCp(PMe3)2(eta1-Pbasal-P4S3)]+ (4) was solved by X-ray diffraction and represents the first example of X-ray structure of intact P4S3 coordinated to a mononuclear ruthenium organometallic fragment. Hydrolysis of the P4 ligand in 3 resulted mainly in two products, i.e. free H3PO3 and the diphosphane complex cation [{RuCp(PMe3)2}2(mu,eta1:1-P2H4)]2+ (9), while in the presence of methanol two mononuclear complexes [RuCp(PMe3)2{P(OH)3}]+ (8) and [RuCp(PMe3)2{P(OCH3)3}]+ (10) in (2:1) ratio were selectively formed.
Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions.HPLC of Formula: C41H35ClP2Ru, you can also check out more blogs about32993-05-8
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI