Synthetic Route of 246047-72-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium. In a document type is Article, introducing its new discovery.
Unsaturated halocarbene complexes can be synthesized in the first example of olefin metathesis with a directly fluorinated substrate. The ruthenium catalyst 1 reacts with 1,1-difluoroethylene to yield the corresponding methylidene [Ru] = CH2 (2) and difluorocarbene [Ru] = CF2 complexes (3). H2IMes = 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene; Cy = cyclohexyl.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI