92361-49-4, Name is Chloro(pentamethylcyclopentadienyl)bis(triphenylphosphine)ruthenium(II), molecular formula is C46H45ClP2Ru, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 92361-49-4, HPLC of Formula: C46H45ClP2Ru
The reaction of [(eta5-L3)Ru(PPh3) 2Cl], where; L3 = C9H7 (1), C 5Me5 (Cp*) (2) with acetonitrile in the presence of [NH4][PF6] yielded cationic complexes [(eta5- L3)Ru(PPh3)2(CH3CN)][PF 6]; L3 = C9H7 ([3]PF6) and L3 = C5Me5 ([4]PF6), respectively. Complexes [3]PF6 and [4]PF6 reacts with some polypyridyl ligands viz, 2,3-bis (alpha-pyridyl) pyrazine (bpp), 2,3-bis (alpha-pyridyl) quinoxaline (bpq) yielding the complexes of the formulation [(eta5-L3)Ru(PPh3)(L2)]PF 6 where; L3 = C9H7, L2 = bpp, ([S]PF6), L3 = C9H7, L 2 = bpq, ([6]PF6); L3 = C5Me 5, L2 = bpp, ([7]PF6) and bpq, ([8]PF 6), respectively. However reaction of [(eta5-C 9H7)Ru(PPh3)2(CH3CN)] [PF6] ([3]PF6) with the sterically demanding polypyridyl ligands, viz. 2,4,6-tris(2-pyridyl)-1,3,5-triazine (tptz) or tetra-2-pyridyl-1,4-pyrazine (tppz) leads to the formation of unexpected complexes [Ru(PPh3)2(L2)(CH3CN)] [PF6]2; L2 = tppz ([9](PF6) 2), tptz ([11](PF6)2) and [Ru(PPh 3)2(L2)Cl][PF6]; L2 = tppz ([10]PF6), tptz ([12]PF6). The complexes were isolated as their hexafluorophosphate salts. They have been characterized on the basis of micro analytical and spectroscopic data. The crystal structures of the representative complexes were established by X-ray crystallography.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.HPLC of Formula: C46H45ClP2Ru. In my other articles, you can also check out more blogs about 92361-49-4
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI