Extracurricular laboratory:new discovery of Dichloro(benzene)ruthenium(II) dimer

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: ruthenium-catalysts. In my other articles, you can also check out more blogs about 37366-09-9

37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, category: ruthenium-catalysts

The reaction of the potentially tridentate phosphinite PCP pincer type ligand [C6H4-1,3-(OPPh2)2] with [(eta6-p-cymene)RuCl2]2 affords the bimetallic species [C6H4-1,3-(OPPh2{Ru(eta 6-p-cymene)Cl2})2]. Several attempts, including the change of the ruthenium starting material (e.g. [(eta6- benzene)RuCl2]2) and reflux conditions to achieve the coordination of the diphosphinite [C6H4-1,3-(OPPh 2)2] in a tridentate PCP pincer fashion failed. Complex [C6H4-1,3-(OPPh2{Ru(eta6-p-cymene) Cl2})2] was tested in the transfer hydrogenation of ketones.

Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.category: ruthenium-catalysts. In my other articles, you can also check out more blogs about 37366-09-9

Reference:
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI