Electric Literature of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
Two homo-trinuclear complexes [{(eta5-C5Me5)RhCl}3(mu3-L)] (1) and [{(eta5-C5H5)Ru(PPh3)}3(mu3-L)] (2) (H3L = 2,4,6-trimercapto-1,3,5-triazine) are reported. Both the complexes have been fully characterized by elemental analyses, FAB-MS, IR, NMR, electronic and emission spectral techniques. Molecular structure of 1 has been authenticated by single crystal X-ray diffraction analyses. Complex 1 revealed the strong intra- and inter-molecular C-H?X (X = Cl, pi) and pi-pi stacking interactions, which play important roles to stabilize crystal space packing. Furthermore, the pi-pi interactions in 1 lead to a double-helical motif.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI