A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article，once mentioned of 37366-09-9, name: Dichloro(benzene)ruthenium(II) dimer
The synthesis and characterization of cationic arene ruthenium compounds [(eta6-p-iPrC6H4Me) RuCl(kappa2-dpa)]BF4 (1), [(eta6-C 6H6)RuCl(kappa2-dpa)]BF4 (2), [(eta6-p-iPrC6H4Me)- RuCl(kappa2-dpb)]BF4 (3), [(eta6-p- iPrC6H4Me)RuCl(kappa2-dpb)]PF 6.CH3OH (4) and [(eta6-C6H 6)-RuCl(kappa2-dpb)]PF6 (5) (arene = C 6H6 or p-iPrC6H4Me; dpa = 2,2?-dipyridylamine and dpb = di-2-pyridylbenzylamine) have been described. Reactions of the representative compounds 1 and 3 with NaN 3, NaCN, and NH4SCN afforded substitution products [(eta6-p-iPrC6H4Me)- Ru(kappa2-dpa)(N3)]BF4 (6), [(eta6-p-iPrC6H4Me) Ru(kappa2-dpa)(CN)]BF4 (7), [(eta6-p- iPrC6H4Me)-Ru(kappa2-dpa)(NCS)] BF4 (8), [(eta6-p-iPrC6H 4Me)Ru(kappa2-dpb)(N3)]BF4 (9), [(eta6-p-iPrC6H4Me)- Ru(kappa2-dpb)(CN)]BF4 (10) and [(eta6-p- iPrC6H4Me)Ru(kappa2-dpb)(NCS)] BF4 (11). The compounds under investigation have been characterized by elemental analyses, spectroscopic and electrochemical studies. Molecular structures of 1, 3, 4 and 5 have been determined crystallographically. The compounds 1-3 and 5 exhibited moderate catalytic activity in the reduction of ketones into corresponding alcohol in absence of a base.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.name: Dichloro(benzene)ruthenium(II) dimer. In my other articles, you can also check out more blogs about 37366-09-9
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI