Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 10049-08-8, Cl3Ru. A document type is Article, introducing its new discovery., name: Ruthenium(III) chloride
The structure of the ultimate product of the interaction of ruthenium with thiourea (Thio) is studied by EPR. From hyperfine coupling (HFC) of the electron to 101Ru, it is found that the complex is a dimer of the tentative composition [{(Thio)5Ru}2(mu-SH)]4+, in which the unpaired electron is localized into the dxz(dyz) orbitals of two equivalent Ru nuclei. The EPR spectra of Ru(III) and Os(III) sulfides and tris-chelates 101Ru(SS)3 (SS is diethyldithiocarbamate, ethylxanthogenate ions) are studied. Interpretation of the g-tensors and HFC and analysis of the relevant literature data indicate that, in mononuclear complexes of Ru(III) and Os(III) bound to the S6 array, the unpaired electron is located into the dxy orbital and is appreciably delocalized to the ligands.
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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI