Reference of 32993-05-8. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
Herein are described some continuing investigations into the reactions of cyano-alkenes with diynyl-ruthenium complexes which have resulted in the preparation and characterisation of diynyl-ruthenium compounds Ru(C?CC?CR)(PP)Cp [R = Ph, PP = dppe; R = Fc, PP = dppf; R = CPh=CBr2, PP = (PPh3)2], together with the polycyanobutadienyls Ru{C?CC[=C(CN)2]CR=CR?(CN)}(PP) Cp? [R = Fc, (PP)Cp? = (dppf)Cp; R = H, SiMe3, (PP)Cp? = (dppe)Cp*] formed by [2 + 2]-cycloaddition of the cyano-alkenes to the outer C?C triple bonds and subsequent ring-opening reactions. Single-crystal XRD molecular structure determinations of six complexes are reported. Copyright
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI