37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Computed Properties of C12H12Cl4Ru2
The chalcogenide ligands {E=PPh2Py} (E = O, S, Se) were prepared by direct oxidation of diphenyl(2-pyridyl)phosphine using H2O2, S, and Se powder, respectively. The reaction of ligand with starting metal precursors [(arene)RuCl2]2 {M = Ru, arene = benzene; p-cymene} and [Cp MCl2]2 (M = Rh, Ir) afforded a series of cationic half-sandwich complexes, [(arene/Cp)MCl{2-(NE)-EPPh2Py)}]+. Reaction of O=PPh2Py with precursors yielded known complexes [(arene/Cp)MCl{2-(PN)-PPh2Py)}]+ instead of expected complexes [(arene/Cp)MCl{2-(NO)-O=PPh2Py)}]+. All new complexes were isolated as counterion and characterized by spectroscopic techniques like FT-IR, NMR, mass, and UV-vis. Some representative complexes were structurally determined by X-ray crystallographic analysis, revealing typical three-legged piano stool geometry around the metal center with a five-membered metallacycle.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Computed Properties of C12H12Cl4Ru2. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI