Related Products of 37366-09-9, Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, get their minds active, and encourage them to do something that doesn’t involve a screen. 37366-09-9, C12H12Cl4Ru2. A document type is Article, introducing its new discovery.
A series of heterodinuclear germanium-ruthenium complexes having sulfido/oxo bridges, Dmp(Dep)-Ge(mu-E1)(mu-E2) Ru(eta6-arene) (E1, E2 = S, O; arene -benzene, p-cymene; Dmp = 2,6-dimesitylphenyl, Dep = 2,6-diethylphenyl) were synthesized by the reaction of [Ru(eta6-arene)Cl2] 2 and the corresponding diarylgermanedichalcogenoles, Dmp(Dep)Ge(E1H)(E2H). The reaction with tertiary phosphines gave the corresponding adducts Dmp(Dep)Ge(mu-S)(mu-E)Ru(PR 3) (E = S, O; R = Ph, Et), in which the arene ligand on the ruthenium was replaced by a mesityl group of Dmp. When Dmp(Dep)Ge(mu-S) 2Ru(PPh3) was treated with the Bronsted acids H(OEt2)2BArF4 and HOTf, a sulfido bridge was protonated to afford [Dmp(Dep)Ge(mu-S)(mu-SH)Ru(PPh 3)]X (X = BArF4, OTf). Likewise, the methylation reaction with Me3OBF4 proceeded at a mu-S, generating [Dmp(Dep)Ge(mu-S)(mu-SMe)Ru(PPh3)](BF4). On the other hand, protonation of Dmp(Dep)Ge(mu-S)(mu-O)Ru(PPh3) gave a mu-OH complex, [Dmp(Dep)Ge(mu-S)(mu-OH)Ru-(PPh3)] +, while the analogous methylation afforded the cationic mu-SMe complex [Dmp(Dep)Ge(mu-SMe)-(mu-O)Ru(PPh3)]+.
If you are hungry for even more, make sure to check my other article about 37366-09-9. Related Products of 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI