Reference of 15746-57-3. Let’s face it, organic chemistry can seem difficult to learn. Especially from a beginner’s point of view. Like 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II). In a document type is Article, introducing its new discovery.
A series of mononuclear and dinuclear Ru(II) complexes of the type [RuL(X)2]n+ and [Ru2L?(X)4]n+, L=L1H, n = 1; L=L+ n=2; L?=L3H2, n=2; L?=L4, n =4 and X=2,2?- bipyridyl as well as 1,10-phenanthroline, have been prepared and characterized by IR, 1H-NMR UV-vis spectra, FAB Mass and elemental analysis data. The complexes display metal-ligand charge-transfer (MLCT) transitions in the visible region and show hyperchromic shift upon addition of DNA solution. Emission observed in the range 580-595 nm is quenched upto 7.3-40.5% upon addition of buffered solution of calf thymus DNA. Acetonitrile solution of the complexes show electrochemical oxidation of the ligands.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI