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Reference of 37366-09-9, An article , which mentions 37366-09-9, molecular formula is C12H12Cl4Ru2. The compound – Dichloro(benzene)ruthenium(II) dimer played an important role in people’s production and life.
The compound CH2=C(CH2SnMe3)2 1 was readily made (61 percent yield) from K2(tmm) (tmm = trimethylenemethane) and SnMe3Cl.It serves as a new and efficient entry to tmm metal complexes.The arene complexes <2> (M = Ru or Os) reacted with 1 to give allylmetal complexes (arene)> 2a-2e and sandwich-like compounds 3a-3e (M = Ru, arene = C6H6 a, C6Me6 b, or p-MeC6H4CHMe2 c; M = Os, arene = C6H6 d or p-MeC6H4CHMe2 e).The cymene complexes 3c and 3e can also be made using the combination CH2=C(CH2Cl)2-Mg-tetrahydrofuran as tmmsource.Treatment of <2> with 1 produced in high yield, and the carbonyl compounds <2> (M = Ru or Os) afforded the tricarbonyl complexes (M = Ru or Os) in good yields.X-Ray crystal structure determinations have been made for 2a, 3a and .The data for the last two show the tmm ligand to be more firmly bonded in the arene complex.
I hope this article can help some friends in scientific research. I am very proud of our efforts over the past few months and hope to 37366-09-9, help many people in the next few years., Reference of 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI