Synthetic Route of 37366-09-9, An article , which mentions 37366-09-9, molecular formula is C12H12Cl4Ru2. The compound – Dichloro(benzene)ruthenium(II) dimer played an important role in people’s production and life.
A series of organometallic arene platinum group metal complexes of the type [(eta6-arene)Ru(L)Cl]PF6 {arene = benzene; p-cymene and hexamethylbenzene, L = N, N? ligands} and [(eta5-Cp*) M(L)Cl]PF6 (where M = Rh(iii) and Ir(iii), L = N, N? ligands) were synthesized. All complexes were isolated as hexafluoridophosphate salts and characterised by elemental analysis, infrared and NMR spectroscopy. The molecular structures of three representative complexes 1, 4 and 9 were determined by single crystal X-ray crystallography. They have a “piano stool” geometry with eta5 and eta6 coordination of the arene ligands. Trypan blue exclusion and DNA fragmentation assays of the synthesized complexes displayed the potent anticancer properties of complexes 5, 6 and 9. Compound 6 shows the highest antitumor activity with a T/C value of 211%.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI