A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 10049-08-8, Name is Ruthenium(III) chloride, molecular formula is Cl3Ru. In a Article，once mentioned of 10049-08-8, Quality Control of: Ruthenium(III) chloride
The formation of ruthenium chloro nitroso complexes upon treatment of Ru(III) and Ru(IV) chloro complexes with sodium nitrite and nitric acid inHCl was studied. At 95-100°C, a NaNO2 : Ru ratio of 4 to 12, and c(HCl) = 1-2 mol/l, the yield of the nitroso chloro complexes is nearly quantitative. The mechanism of nitro-sation of ruthenium complexes is p roposed to involve the reduction of Ru(IV) to Ru(III) by nitrous acid and the reaction of ruthenium(III) complexes with nitrogen(II) oxide.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.Quality Control of: Ruthenium(III) chloride, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 10049-08-8, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI