In an article, published in an article, once mentioned the application of 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer,molecular formula is C12H12Cl4Ru2, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C12H12Cl4Ru2
Reactions of [RuCl2(eta6-arene)]2 with ammonium salt of dialkyldithiophosphoric acid in 1 : 1 and 1 : 2 stoichiometry readily gave complexes of the type [Ru{SSP(OR)2}(Cl)(eta6-arene)] (arene = benzene, p-cymene; R = Et, nPr, 1Pr, nBu or sBu) and [Ru{SSP(OR)2}2(eta6-arene)] (R = Et; arene = p-cymene). The former complexes, on treatment with NaBPh4 in acetone followed by addition of a neutral donor ligand (L), afforded cationic complexes [Ru{SSP(OEt)2}(eta6-p-cymene)L][BPh4] (L = py, PPh3, (p-FC6H4)3P, AsPh3]. All the complexes were characterized by elemental analysis and NMR (1H, 31P) data. A single crystal X-ray structure determination of [Ru{SSP(OEt)2}(eta6-p-cymene)(PPh3)][BPh4] has established an octahedral configuration around the ruthenium atom. The structure consists of a ruthenium centre bonded to an eta6-p-cymene, a chelated dithiophosphate and a unidentate triphenylphosphine ligand.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI