37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2, belongs to ruthenium-catalysts compound, is a common compound. In a patnet, once mentioned the new application about 37366-09-9, Recommanded Product: 37366-09-9
The “one-pot” generation of a tris-cationic homobimetallic racemic planar-chiral ruthenacyclic ruthenium sandwich complex from a reaction of the metal-free chelating ligand with the (-6-benzene) dichloridoruthenium(II) dimer in acetonitrile is reported. This unexpected complex, which was characterized by structural X-ray diffraction analysis, is the product of a multistep process entailing first the cycloruthenation of the ligand, a ligand exchange reaction, and eventually the site-selective pi-bonding of a bis-cationic [(-6-benzene)Ru]2+ moiety to a monocationic ruthenacyclic intermediate. Investigations of the underlying electronic structure and bonding scheme by resorting to quantum chemical methods of the density functional theory have revealed the key role played by the electron-donating NMe2 substituent, which enables the a priori antagonistic pi-coordination of the in situ-formed cationic ruthenacycle by a dicationic (-6-arene) ruthenium(II) moiety. Experimental evidence indicates indeed that, in the absence of such an electron-donating group at the metalacycle, the pi-coordination of the [(-6-benzene)Ru] 2+ cannot take place.
Balanced chemical reaction does not necessarily reveal either the individual elementary reactions by which a reaction occurs or its rate law.Recommanded Product: 37366-09-9. In my other articles, you can also check out more blogs about 37366-09-9
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI