Discovery of Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II)

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Synthetic Route of 32993-05-8, An article , which mentions 32993-05-8, molecular formula is C41H35ClP2Ru. The compound – Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II) played an important role in people’s production and life.

New ferrocenyl-based bimetallic cationic compounds of the type of (E)-[CpFe(eta5-C5H4)-(CH=CH)- (C6H4)-CN-RuCp(PPh3)2]X (X=PF6, BF4) and of (E)-[CpFe(eta5-C5H4)-(CH=CH)- (C6H4)-CN-FeCp(CO)2]PF6 have been obtained and characterized. The crystal structure of (E)-[CpFe(eta5-C5H4)-(CH=CH)- (C6H4)-CN-RuCp(PPh3)2] BF4 has been established by means of X-ray diffractometry. The NLO responses of the compounds have been studied by the hyper-Rayleigh scattering technique and the hyperpolarizability is found to be dependent on the nature of the counterion.

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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI