A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II), molecular formula is C20H16Cl2N4Ru. In a Article，once mentioned of 15746-57-3, COA of Formula: C20H16Cl2N4Ru
A series of mononuclear and dinuclear mercury(i), mercury(ii), nickel(ii), lanthanum(iii), ferrous(ii) and ruthenium(ii) complexes 4-11 with different metal/ligand molar ratios (1:1, 1:2 and 1:3), having 2-thiophenimidazo[4,5-f[[1, 10[phenanthroline (TIP) and 2-(5-bromothiophen)imidazo[4,5-f][1, 10[phenanthroline (5-Br-TIP) ligands, have been synthesized and structurally compared. In addition, three protonated salts of TIP and 5-Br-TIP (1-3) with PF6- and ClO4- counterions have been described herein where the proton is found to be located at one of the nitrogen atoms of 1,10-phenanthroline moiety. It is notable that the whole molecules of dinuclear mercury(i) and nickel(ii) complexes 6 and 7 exhibit excellent planarity in the lengths of 2.52 and 2.90 nm, respectively. UV-Vis, 1H NMR and luminescence spectra of ligands TIP and 5-Br-TIP, protonated salts 1-3 and metal complexes 4-11 have also been studied and compared.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.COA of Formula: C20H16Cl2N4Ru, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 15746-57-3, in my other articles.
Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI