Related Products of 32993-05-8. Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II). In a document type is Article, introducing its new discovery.
Two new, air-stable BINAP complexes of ruthenium(II), (RCp)Ru(S-(-)-BINAP)Cl (R = H, CH3) have been prepared in good yield from the reaction of (RCp)Ru(PPh3)2Cl with S-(-)-BINAP in refluxing toluene.The structure of the methylcyclopentadienyl analog has been determined by X-ray crystallography.Both complexes have been found to be effective homogeneous catalysts for the enantioselective hydrogenation of beta-ketoesters.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI