Final Thoughts on Chemistry for Ruthenium(III) chloride

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The reaction velocity follows first-order kinetics with respect to the organic substrate at its lower concentrations and tends to become zero order at higher concentrations in the presence of ruthenium(III). The reaction follows first-order kinetics with respect to ruthenium(III) chloride. On the other hand, the rate of the reaction is directly proportional to the lower concentrations of ruthenium(VIII), but at higher catalyst concentrations the calalytic behavior is decreased. The reaction rate shows direct proportionality with respect to the organic substrate in the presence of ruthenium(VIII).

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Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI