Related Products of 32993-05-8, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.32993-05-8, Name is Chlorocyclopentadienylbis(triphenylphosphine)ruthenium(II), molecular formula is C41H35ClP2Ru. In a patent, introducing its new discovery.
Acid-promoted hydrogen migration in (2-allylphenoxo)ruthenium(II) to form an eta3-allyl complex
Treatment of RuCP[OC6H4(CH2CH=CH 2)-kappa1O: eta2C,C?](PPh 3) (3c) with a Bronsted acid (HX) such as 2-al-lylphenol results in facile migration of a benzylic proton to the aryloxide, giving the (eta3-allyl)ruthenium(II) complex RuCp[CH2-CHCH(C 6H4OH-2)-eta3 C,C?,C?](PPh 3) (Ac). Thermodynamic and kinetic studies suggest that 3c associates with acid to give 3c · HX, and further addition of HX to 3c · HX causes the C-H bond cleavage reaction to give 4c.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI