Synthetic Route of 246047-72-3, Chemistry can be defined as the study of matter and the changes it undergoes. You’ll sometimes hear it called the central science because it is the connection between physics and all the other sciences, starting with biology.246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium, molecular formula is C46H65Cl2N2PRu. In a patent, introducing its new discovery.
The first ansa-nickelocenes, [Ni(eta5,eta5-C 5H4-CH2-CH=CH-CH2-C 5H4)] (4) and [Ni(eta5,eta5- C5H4(CH2)2-CH=CH-(CH 2)2-C5H4)] (5), and a bridged binickelocene, [Ni2(eta5,eta5-C 5H4-(CH2)2-CH=CH(CH 2)2-CsH4)2] (6), were prepared by alkene metathesis of 1,1?-disubstituted nickelocenes. Compound 4 reacts with hydrogen to yield ansa-nickelocene 7, bearing the saturated bridge. The new compounds were characterized by UV-vis, IR, MS, 1H NMR, magnetic susceptibility, and electrochemical measurements. Crystal and molecular structures of 4, 6, and 7 were determined by single-crystal X-ray analysis. These measurements show that the studied ansa-nickelocenes exhibit properties similar to those of nickelocene.
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Reference：
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI