In an article, published in an article, once mentioned the application of 246047-72-3, Name is (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium,molecular formula is C46H65Cl2N2PRu, is a conventional compound. this article was the specific content is as follows.HPLC of Formula: C46H65Cl2N2PRu
Ligand Substitution of RuII?Alkylidenes to Ru(bpy)32+: Sequential Olefin Metathesis/Photoredox Catalysis
Ruthenium(II) alkylidene complexes such as the Grubbs? 1st and 2nd generation catalysts undergo a ligand substitution with 2,2?-bipyridine, which readily leads to the common photoredox catalyst Ru(bpy)32+. The application of this catalyst transformation in sequential olefin metathesis/photoredox catalysis is demonstrated by way of ring-closing metathesis (RCM)/photoredox ATRA reactions.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI