The Absolute Best Science Experiment for 246047-72-3

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Reference of 246047-72-3, An article , which mentions 246047-72-3, molecular formula is C46H65Cl2N2PRu. The compound – (1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene)dichloro(phenylmethylene)(tricyclohexylphosphine)ruthenium played an important role in people’s production and life.

Preparation of seven-membered carbocycles using ring-closing metathesis reaction and application to syntheses of tormesol and cyathane skeleton

Various precursors were synthesized and were reacted with the Grubbs reagent as well as the second generation Grubbs reagent to cyclize them into seven-membered carbocycles with di- or tri-substituted double bonds. These reactions were used to synthesize (-)-tormesol, which is an enantiomer of sphenolobane-type diterpene that was isolated from Halimium viscosum, and a basic skeleton of cyathane-type diterpene.

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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI