In an article, published in an article, once mentioned the application of 15746-57-3, Name is Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II),molecular formula is C20H16Cl2N4Ru, is a conventional compound. this article was the specific content is as follows.Quality Control of: Cis-Dichlorobis(2,2′-bipyridine)ruthenium(II)
Synthesis, photophysical, and electrochemical properties of two novel trinuclear Ru(II) polypyridyl complexes
Two polypyridyl ligands 2,2?,2?-tris((4,5-diazafluoren-9-yliminoxy)ethyl)amine (L1) and 1,3,5-tris((4,5-diazafluoren-9-yliminoxy)methyl))-2,4,6-trimethylbenzene (L2), and corresponding trinuclear Ru(II) complexes [(bpy)6L1-2(RuII)3](PF6)6 (Ru-L1, Ru-L2) have been synthesized. Cyclic voltammetry of the complexes are consistent with one Ru(II)-centered oxidation at 1.32 V and four ligand-centered reductions. Photophysical behaviors are investigated by UV-Vis absorption and fluorescence spectrometry. The two complexes show metal-to-ligand charge transfer absorption at 440 nm and emission at around 580 nm.
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Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI