A catalyst don’t appear in the overall stoichiometry of the reaction it catalyzes, but it must appear in at least one of the elementary reactions in the mechanism for the catalyzed reaction. 37366-09-9, Name is Dichloro(benzene)ruthenium(II) dimer, molecular formula is C12H12Cl4Ru2. In a Article£¬once mentioned of 37366-09-9, COA of Formula: C12H12Cl4Ru2
Syntheses, spectral and structural characterization of eta5- and eta6-cyclic pi-perimeter hydrocarbon platinum group metal complexes containing pyridazine-NHC analogues
A family of platinum group metal complexes containing bidentate pyridazine-NHC ligands (L1 = 3,6-bis(N-n-methylimidazolyl)pyridazine dichloride, L2 = 3,6-bis(N-n-butylimidazolyl)pyridazine dichloride) have been synthesized. The typical mechanism of the reactions for these syntheses involved an in situ carbene transfer reactions. Reaction of L1/L2 with silver oxide in absence of light yielded silver-NHC complexes (1) and (2). When, the respective metal precursors were added to the silver-NHC complexes, transmetallation occurred with the possible isolation of the following cationic complexes: [(eta6-C6H6)Ru(L)Cl]2+ {L = L1 (3), L2 (5)}, [(eta6-p-iPrC6H 4Me)Ru(L)Cl]2+ {L = L1 (4), L2 (6)}, [Cp *Rh(L)Cl]2+ {L = L1 (7), L2 (9)} and [Cp *Ir(L)Cl]2+ {L = L1 (8), L2 (10)}. All these complexes were stable in ambient atmosphere, and could be obtained in good yield. All these complexes were characterized by spectroscopic analyses. The molecular structure of the complex 9 was determined by single crystal X-ray diffraction studies.
Sometimes chemists are able to propose two or more mechanisms that are consistent with the available data.COA of Formula: C12H12Cl4Ru2, If a proposed mechanism predicts the wrong experimental rate law, however, the mechanism must be incorrect.Welcome to check out more blogs about 37366-09-9, in my other articles.
Reference£º
Highly efficient and robust molecular ruthenium catalysts for water oxidation,
Catalysts | Special Issue : Ruthenium Catalysts – MDPI